A well-defined silica-supported aluminium alkyl through an unprecedented, consecutive two-step protonolysis–alkyl transfer mechanism

J. Pelletier, J. Espinas, N. Vu, S. Norsic, A. Baudouin, L. Delevoye, J. Trébosc, E. Le Roux, C. Santini, J.-M. Basset, R.M. Gauvin, M. Taoufik
Chem. Commun., 47, pp. 2979-2981, (2011)

A well-defined silica-supported aluminium alkyl through an unprecedented, consecutive two-step protonolysis–alkyl transfer mechanism

Keywords

Mesoporous material

Abstract

​Impregnation of [(AliBu3)(Et2O)] on partially dehydroxylated SBA-15 affords a mesoporous material bearing the well-defined single site surface aluminium species [([triple bond, length as m-dash]SiO)2Al(iBu)(Et2O)].

Code

DOI: 10.1039/C0CC04986G

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