A facile metal-free “grafting-from” route from acrylamide-based substrate toward complex macromolecular combs

J. Zhao, H. Alamri, N. Hadjichristidis
Chem. Commun., 49, 7079-7081, (2013)

A facile metal-free “grafting-from” route from acrylamide-based substrate toward complex macromolecular combs

Keywords

Macromolecular combs

Abstract

​High-molecular-weight poly(N,N-dimethylacrylamide-co-acrylamide) was used as a model functional substrate to investigate phosphazene base (t-BuP4)-promoted metal-free anionic graft polymerization utilizing primary amide moieties as initiating sites. The (co)polymerization of epoxides was proven to be effective, leading to macromolecular combs with side chains being single- or double-graft homopolymer, block copolymer and statistical copolymer.

Code

DOI: 10.1039/C3CC44131H

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