Selective hydrogen generation from formic acid with well-defined complexes of ruthenium and phosphorus-nitrogen PN3-pincer ligand

Y. Pan, C.-L. Pan, Y. Zhang, H. Li, S. Min, X. Guo, B. Zheng, H. Chen, A. Anders, Z. Lai, J. Zheng, K.-W. Huang
Chemistry-An Asian Journal, 11, 1357-1360, (2016)

Selective hydrogen generation from formic acid with well-defined complexes of ruthenium and phosphorus-nitrogen PN3-pincer ligand

Keywords

PN3-pincer

Abstract

An unsymmetrically protonated PN3-pincer complex in which ruthenium is coordinated by one nitrogen and two phosphorus atoms was employed for the selective generation of hydrogen from formic acid. Mechanistic studies suggest that the imine arm participates in the formic acid activation/deprotonation step. A long life time of 150 h with a turnover number over 1 million was achieved.

Code

DOI: 10.1002/asia.201600169

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