Chemistry of Anilido Phosphine Complexes of Nickel

X.R. Zou, S.M. Liao, K.W. Huang, L.C. Liang
Chemistry Letters, (2019)

Chemistry of Anilido Phosphine Complexes of Nickel

Keywords

PNP Pincer, NP Chelate, C-H activation

Abstract

​The chemistry of anilido phosphine complexes has been popularized since 2003 when N-arylation of the parent o-anilinophosphine was made possible. This Highlight Review summarizes the cumulative progress made in nickel chemistry, paying particular attention to oxidative addition, reductive elimination, CO insertion, olefin insertion, β-hydrogen elimination, metathetical reaction, arene C-H activation, and their collaborative applications to Kumada-type cross coupling catalysis.

Code

DOI: 10.1246/cl.190216

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